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Light‐Driven Activation of the [H 2 O(terpy)Mn III ‐μ‐(O 2 )‐Mn IV (terpy)OH 2 ] Unit in a Chromophore–Catalyst Complex
Author(s) -
Herrero Christian,
Quaranta Annamaria,
Protti Stefano,
Leibl Winfried,
Rutherford A. William,
Fallahpour Dr Reza,
Charlot MarieFrance,
Aukauloo Ally
Publication year - 2011
Publication title -
chemistry – an asian journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.18
H-Index - 106
eISSN - 1861-471X
pISSN - 1861-4728
DOI - 10.1002/asia.201100030
Subject(s) - chromophore , electron paramagnetic resonance , catalysis , ruthenium , photochemistry , chemistry , daylight , organic chemistry , physics , optics , nuclear magnetic resonance
The Living Daylight : Ruthenium‐based chromophores are employed as building blocks for a photo‐active complex bearing a known water‐oxidation catalytic system [(Terpy) 2 (Mn III ‐μ‐(O 2 )‐Mn IV )]. Its activation by visible light has been studied by EPR spectroscopy.