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Rate‐Acceleration in Gold‐Nanocluster‐Catalyzed Aerobic Oxidative Esterification Using 1,2‐ and 1,3‐Diols and Their Derivatives
Author(s) -
Yasukawa Tomohiro,
Miyamura Hiroyuki,
Kobayashi Shū
Publication year - 2011
Publication title -
chemistry – an asian journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.18
H-Index - 106
eISSN - 1861-471X
pISSN - 1861-4728
DOI - 10.1002/asia.201000624
Subject(s) - nanoclusters , catalysis , methanol , chemistry , oxidative phosphorylation , diol , organic chemistry , combinatorial chemistry , biochemistry
Aerobic oxidation of aldehydes to 1,2‐ and 1,3‐diol monoesters was catalyzed by polymer‐incarcerated gold nanoclusters under ambient conditions. The esterification proceeded much faster with 1,2‐ and 1,3‐diols and their derivatives rather than with methanol.