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Hydrosilylation of Ketones : From Metal–Organic Frameworks to Simple Base Catalysts
Author(s) -
Addis Daniele,
Zhou Shaolin,
Das Shoubhik,
Junge Kathrin,
Kosslick Hendrik,
Harloff Jörg,
Lund Henrik,
Schulz Axel,
Beller Matthias
Publication year - 2010
Publication title -
chemistry – an asian journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.18
H-Index - 106
eISSN - 1861-471X
pISSN - 1861-4728
DOI - 10.1002/asia.201000427
Subject(s) - hydrosilylation , catalysis , methanol , sodium hydroxide , chemistry , base (topology) , potassium hydroxide , potassium , sodium , organic chemistry , metal , organic base , polymer chemistry , mathematical analysis , mathematics
A convenient base‐catalyzed hydrosilylation of aromatic ketones using inexpensive bases, such as 1 M sodium hydroxide in methanol or sodium/potassium tert ‐butoxide, has been developed. Mild reaction conditions (room temperature, 1 h) successfully promote the hydrosilylation of a variety of ketones.