Hydrosilylation of Ketones : From Metal–Organic Frameworks to Simple Base Catalysts | Zendy

Addis Daniele | Zendy; Zhou Shaolin | Zendy; Das Shoubhik | Zendy; Junge Kathrin | Zendy; Kosslick Hendrik | Zendy; Harloff Jörg | Zendy; Lund Henrik | Zendy; Schulz Axel | Zendy; Beller Matthias | Zendy

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Hydrosilylation of Ketones : From Metal–Organic Frameworks to Simple Base Catalysts

Author(s) -

Addis Daniele,

Zhou Shaolin,

Das Shoubhik,

Junge Kathrin,

Kosslick Hendrik,

Harloff Jörg,

Lund Henrik,

Schulz Axel,

Beller Matthias

Publication year - 2010

Publication title -

chemistry – an asian journal

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.18

H-Index - 106

eISSN - 1861-471X

pISSN - 1861-4728

DOI - 10.1002/asia.201000427

Subject(s) - hydrosilylation , catalysis , methanol , sodium hydroxide , chemistry , base (topology) , potassium hydroxide , potassium , sodium , organic chemistry , metal , organic base , polymer chemistry , mathematical analysis , mathematics

A convenient base‐catalyzed hydrosilylation of aromatic ketones using inexpensive bases, such as 1 M sodium hydroxide in methanol or sodium/potassium tert ‐butoxide, has been developed. Mild reaction conditions (room temperature, 1 h) successfully promote the hydrosilylation of a variety of ketones.

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