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An Iron(II) Carbonyl Thiolato Complex Bearing 2‐Methoxy‐Pyridine: A Structural Model of the Active Site of [Fe] Hydrogenase
Author(s) -
Tanino Soichiro,
Ohki Yasuhiro,
Tatsumi Kazuyuki
Publication year - 2010
Publication title -
chemistry – an asian journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.18
H-Index - 106
eISSN - 1861-471X
pISSN - 1861-4728
DOI - 10.1002/asia.201000408
Subject(s) - pyridine , hydrogenase , active site , bearing (navigation) , chemistry , combinatorial chemistry , stereochemistry , computer science , catalysis , medicinal chemistry , biochemistry , artificial intelligence
Model complex : An Fe II complex bearing a thiolate, 2‐methoxy‐pyridine, and three facially arranged CO ligands was synthesized as a structural analogue of the active site of a CO‐inhibited form of [Fe] hydrogenase, from the reaction of [FeBr 2 (CO) 4 ] with NaS{2,6‐(mesityl) 2 C 6 H 3 } and the successive treatment with 2‐methoxy‐pyridine.