An Iron(II) Carbonyl Thiolato Complex Bearing 2‐Methoxy‐Pyridine: A Structural Model of the Active Site of [Fe] Hydrogenase | Zendy

Tanino Soichiro | Zendy; Ohki Yasuhiro | Zendy; Tatsumi Kazuyuki | Zendy

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An Iron(II) Carbonyl Thiolato Complex Bearing 2‐Methoxy‐Pyridine: A Structural Model of the Active Site of [Fe] Hydrogenase

Author(s) -

Tanino Soichiro,

Ohki Yasuhiro,

Tatsumi Kazuyuki

Publication year - 2010

Publication title -

chemistry – an asian journal

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.18

H-Index - 106

eISSN - 1861-471X

pISSN - 1861-4728

DOI - 10.1002/asia.201000408

Subject(s) - pyridine , hydrogenase , active site , bearing (navigation) , chemistry , combinatorial chemistry , stereochemistry , computer science , catalysis , medicinal chemistry , biochemistry , artificial intelligence

Model complex : An Fe II complex bearing a thiolate, 2‐methoxy‐pyridine, and three facially arranged CO ligands was synthesized as a structural analogue of the active site of a CO‐inhibited form of [Fe] hydrogenase, from the reaction of [FeBr 2 (CO) 4 ] with NaS{2,6‐(mesityl) 2 C 6 H 3 } and the successive treatment with 2‐methoxy‐pyridine.

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