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Catalyst versus Substrate Induced Selectivity: Kinetic Resolution by Palladacycle Catalyzed Allylic Imidate Rearrangements
Author(s) -
Peters René,
Xin Zhuoqun,
Maier Frank
Publication year - 2010
Publication title -
chemistry – an asian journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.18
H-Index - 106
eISSN - 1861-471X
pISSN - 1861-4728
DOI - 10.1002/asia.201000386
Subject(s) - allylic rearrangement , selectivity , kinetic resolution , catalysis , substrate (aquarium) , olefin fiber , chemistry , combinatorial chemistry , kinetic energy , resolution (logic) , stereochemistry , computer science , organic chemistry , enantioselective synthesis , physics , geology , artificial intelligence , oceanography , quantum mechanics
Making chairs : A kinetic resolution of allylic imidates by planar chiral palladacycles is described which is the result of high face selectivity for olefin coordination to the catalyst and inherent substrate selectivity. These studies confirm that planar chiral palladacycles mainly operate via (half)chair‐like transition states/intermediates.