Palladium‐Catalyzed Intramolecular Carboacetoxylation of 4‐Pentenyl‐Substituted Malonate Esters with Iodobenzene Diacetate | Zendy

Fujino Daishi | Zendy; Yorimitsu Hideki | Zendy; Oshima Koichiro | Zendy

Premium

Palladium‐Catalyzed Intramolecular Carboacetoxylation of 4‐Pentenyl‐Substituted Malonate Esters with Iodobenzene Diacetate

Author(s) -

Fujino Daishi,

Yorimitsu Hideki,

Oshima Koichiro

Publication year - 2010

Publication title -

chemistry – an asian journal

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.18

H-Index - 106

eISSN - 1861-471X

pISSN - 1861-4728

DOI - 10.1002/asia.201000194

Subject(s) - iodobenzene , palladium , malonate , intramolecular force , catalysis , chemistry , cyclopentanes , organic chemistry , bicyclic molecule , medicinal chemistry

The motorcyclization diaries : Palladium‐catalyzed intramolecular carboacetoxylation of 4‐pentenyl‐substituted malonates proceeds with the aid of titanium tetraisopropoxide and iodobenzene diacetate. The transformation represents the first Pd II /Pd IV catalytic oxidative process that forms an C sp 3 C sp 3 bond as well as a useful method for the synthesis of acetoxymethyl‐substituted cyclopentanes or bicyclic lactones.

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here

Accelerating Research