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Rh I ‐Catalyzed Two‐Component [(5+2)+1] Cycloaddition Approach toward [5‐8‐5] Ring Systems
Author(s) -
Huang Feng,
Yao ZhongKe,
Wang Yi,
Wang Yuanyuan,
Zhang Jialing,
Yu ZhiXiang
Publication year - 2010
Publication title -
chemistry – an asian journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.18
H-Index - 106
eISSN - 1861-471X
pISSN - 1861-4728
DOI - 10.1002/asia.201000053
Subject(s) - cycloaddition , component (thermodynamics) , ring (chemistry) , catalysis , atom (system on chip) , chemistry , computer science , tricyclic , combinatorial chemistry , stereochemistry , organic chemistry , parallel computing , physics , thermodynamics
Bringing it all together : [{Rh(CO) 2 Cl} 2 ]‐catalyzed two‐component [(5+2)+1] cycloaddition of ene‐vinylcyclopropanes with various tether types and substituents with CO has been designed for the one‐pot synthesis of fused tricyclic cyclooctenones with atom and step economies.