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A Structural Model for HPO 4 2− Binding to Co in a Water Oxidation Catalyst
Author(s) -
McClintock Lisa F.,
Blackman Allan G.
Publication year - 2010
Publication title -
chemistry – an asian journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.18
H-Index - 106
eISSN - 1861-471X
pISSN - 1861-4728
DOI - 10.1002/asia.200900728
Subject(s) - catalysis , chemistry , transition metal , metal , crystallography , organic chemistry
How might it bind? The X‐ray structural characterization of the first example of chelated HPO 4 2− in a mononuclear transition‐metal complex provides a possible model for HPO 4 2− bonding to Co III in the water oxidation catalyst isolated by Kanan and Nocera.