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Perceptible Influence of Pd and Pt Heterocyclic Carbene–Pyridyl Complexes in Catalytic Diboration of Cyclic Alkenes
Author(s) -
PubillUlldemolins Cristina,
Bo Carles,
Mata Jose A.,
Fernández Elena
Publication year - 2010
Publication title -
chemistry – an asian journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.18
H-Index - 106
eISSN - 1861-471X
pISSN - 1861-4728
DOI - 10.1002/asia.200900580
Subject(s) - carbene , catalysis , chemistry , strain (injury) , medicinal chemistry , photochemistry , organic chemistry , medicine
No strain, no gain : Bis(catecholato)diboron was added to cyclic alkenes with internal strain to selectively form bis(boryl)cycloalkanes quantitatively in the presence of [Pd(NHC)pyCl 2 ], [Pd(NHC)pyI 2 ], and [Pt(NHC)pyI 2 ] (NHC=N‐heterocyclic carbene, py=pyridyl), which have been synthesized and characterized for the first time in this study.