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Regioselective Silylzincation of Phenylallene Derivatives
Author(s) -
Yonehara Mitsuhiro,
Nakamura Shinji,
Muranaka Atsuya,
Uchiyama Masanobu
Publication year - 2010
Publication title -
chemistry – an asian journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.18
H-Index - 106
eISSN - 1861-471X
pISSN - 1861-4728
DOI - 10.1002/asia.200900452
Subject(s) - vinylsilane , regioselectivity , reagent , key (lock) , combinatorial chemistry , chemistry , stereochemistry , organic chemistry , computer science , catalysis , operating system
Pick your choice : This paper deals with our new approach for regio‐controlled synthesis of exo / endo ‐vinylsilanes through silylzincation as a key reaction, using newly developed silylzinc reagents. In this system, by choosing appropriate zinc reagents, either exo ‐vinylsilane or endo ‐vinylsilane can be synthesized with good regioselectivity, using the same phenylallene substrates.