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Fluorous Pores in Coordination Networks
Author(s) -
Jang Minsul,
Yamaguchi Takumi,
Ohara Kazuaki,
Kawano Masaki,
Fujita Makoto
Publication year - 2009
Publication title -
chemistry – an asian journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.18
H-Index - 106
eISSN - 1861-471X
pISSN - 1861-4728
DOI - 10.1002/asia.200900293
Subject(s) - bridging (networking) , nanoscopic scale , nanotechnology , coordination complex , liquid phase , computer science , phase (matter) , chemistry , materials science , physics , organic chemistry , computer network , metal , thermodynamics
Fluorous nanophase in the pore : Perfluoroalkyl chain‐anchored bridging ligands are assembled, upon complexation with Co(NCS) 2 , into coordination networks with fluorous pores that show fluorophilic/organophobic properties. The perfluoroalkyl chains are considerably disordered and seem to tumble in the pores, forming a nanoscopic pseudo liquid phase in the solid.