Fluorous Pores in Coordination Networks | Zendy

Jang Minsul | Zendy; Yamaguchi Takumi | Zendy; Ohara Kazuaki | Zendy; Kawano Masaki | Zendy; Fujita Makoto | Zendy

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Fluorous Pores in Coordination Networks

Author(s) -

Jang Minsul,

Yamaguchi Takumi,

Ohara Kazuaki,

Kawano Masaki,

Fujita Makoto

Publication year - 2009

Publication title -

chemistry – an asian journal

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.18

H-Index - 106

eISSN - 1861-471X

pISSN - 1861-4728

DOI - 10.1002/asia.200900293

Subject(s) - bridging (networking) , nanoscopic scale , nanotechnology , coordination complex , liquid phase , computer science , phase (matter) , chemistry , materials science , physics , organic chemistry , computer network , metal , thermodynamics

Fluorous nanophase in the pore : Perfluoroalkyl chain‐anchored bridging ligands are assembled, upon complexation with Co(NCS) 2 , into coordination networks with fluorous pores that show fluorophilic/organophobic properties. The perfluoroalkyl chains are considerably disordered and seem to tumble in the pores, forming a nanoscopic pseudo liquid phase in the solid.

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