A DBFOX‐Ph‐Based Combinatorial Catalyst for Enantioselective Fluorination of Aryl Acetyl and 3‐Butenoyl Thiazolidinones | Zendy

Reddy Dhande Sudhakar | Zendy; Shibata Norio | Zendy; Horikawa Takao | Zendy; Suzuki Satoru | Zendy; Nakamura Shuichi | Zendy; Toru Takeshi | Zendy; Shiro Motoo | Zendy

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A DBFOX‐Ph‐Based Combinatorial Catalyst for Enantioselective Fluorination of Aryl Acetyl and 3‐Butenoyl Thiazolidinones

Author(s) -

Reddy Dhande Sudhakar,

Shibata Norio,

Horikawa Takao,

Suzuki Satoru,

Nakamura Shuichi,

Toru Takeshi,

Shiro Motoo

Publication year - 2009

Publication title -

chemistry – an asian journal

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.18

H-Index - 106

eISSN - 1861-471X

pISSN - 1861-4728

DOI - 10.1002/asia.200900164

Subject(s) - enantioselective synthesis , aryl , catalysis , combinatorial chemistry , chemistry , combinatorial synthesis , organic chemistry , alkyl

The catalytic asymmetric fluorination for aryl acetyl and 3‐butenoyl thiazolidinones was achieved with extremely high enantioselectivity by the use of a combinatorial catalyst, DBFOX‐Ph/Ni II /HFIP/2,6‐lutidine, and provides an effective entry to chiral α‐fluorinated compounds. The combinatorial catalyst system is also applicable to the first enantioselective α‐chlorination of aryl acetyl thiazolidinones.

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