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Asymmetric Ligand‐Exchange Reaction of Biphenol Derivatives and Chiral Bis(oxazolinyl)phenyl–Rhodium Complex
Author(s) -
Inoue Hiroko,
Ito Junichi,
Kikuchi Makoto,
Nishiyama Hisao
Publication year - 2008
Publication title -
chemistry – an asian journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.18
H-Index - 106
eISSN - 1861-471X
pISSN - 1861-4728
DOI - 10.1002/asia.200800059
Subject(s) - rhodium , ligand (biochemistry) , chemistry , medicinal chemistry , stereochemistry , organic chemistry , catalysis , receptor , biochemistry
Chiral bis(oxazolinyl)phenyl–rhodium acetate complex can enantioselectively capture 1,1′‐binaphthol derivatives by ligand‐exchange reaction. The structure of the bis(oxazolinyl)phenyl–rhodium biphenol and binaphthol complexes were confirmed by X‐ray analysis.
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