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Single‐Crystalline and Near‐Monodispersed NaMF 3 (M=Mn, Co, Ni, Mg) and LiMAlF 6 (M=Ca, Sr) Nanocrystals from Cothermolysis of Multiple Trifluoroacetates in Solution
Author(s) -
Du YaPing,
Zhang YaWen,
Yan ZhengGuang,
Sun LingDong,
Gao Song,
Yan ChunHua
Publication year - 2007
Publication title -
chemistry – an asian journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.18
H-Index - 106
eISSN - 1861-471X
pISSN - 1861-4728
DOI - 10.1002/asia.200700054
Subject(s) - oleylamine , nanocrystal , nanorod , materials science , photon upconversion , luminescence , photoluminescence , analytical chemistry (journal) , chemical engineering , nanotechnology , chemistry , optoelectronics , organic chemistry , engineering
Abstract We report the synthesis of single‐crystalline and near‐monodispersed NaMF 3 (M=Mn, Co, Ni, Mg), LiMAlF 6 (M=Ca, Sr), and NaMgF 3 :Yb,Er nanocrystals (quasisquare nanoplates, nanorods, and nanopolygons) by the cothermolysis of multiple trifluoroacetates in hot combined organic solvents (oleic acid, oleylamine, and 1‐octadecene). The nanocrystals were characterized by XRD, TEM, superconductive quantum interference device (SQUID), and upconversion luminescence spectroscopy. By regulating the polarity of the dispersant, the NaMF 3 (M=Mn, Co, Ni) nanoplates were partially aligned to form nanoarrays on copper TEM grids. The sizes of the NaMF 3 nanocrystals were easily tuned by the use of proper synthetic conditions such as reaction temperature and time and solvent composition. On the basis of a series of experiments in which the reaction conditions were varied, together with GC–MS and FTIR analysis, the reaction pathways for the formation of these nanocrystals from trifluoroacetate precursors were proposed. The magnetic measurements showed that the differently sized NaMnF 3 square plates displayed interesting weak ferromagnetic behavior on the nanometer scale. The strong red upconversion luminescence emitted from the NaMgF 3 :Yb,Er nanorods under 980‐nm near‐IR laser excitation suggests that NaMgF 3 may be a good candidate host material for red upconversion luminescence.