Premium
Silver‐Catalyzed Asymmetric Allylation: Allyltrimethoxysilane as a Remarkable Reagent
Author(s) -
Yamamoto Hisashi,
Wadamoto Manabu
Publication year - 2007
Publication title -
chemistry – an asian journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.18
H-Index - 106
eISSN - 1861-471X
pISSN - 1861-4728
DOI - 10.1002/asia.200600413
Subject(s) - enantioselective synthesis , reagent , catalysis , chemistry , fluoride , combinatorial chemistry , organic chemistry , metal , inorganic chemistry
Recently, there have been some reports on the use of allyltrimethoxysilane for enantioselective allylation with various metal fluorides or a combination of chiral complex and fluoride anion. These reactions can be applied not only to aldehydes but also to ketones and imines. In this Focus Review we discuss the development of asymmetric allylation with allyltrimethoxysilane catalyzed by chiral silver complexes.