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Diffusion‐Influenced Reversible Trapping Problem in the Presence of an External Field
Author(s) -
Park Soohyung,
Shin Kook Joe
Publication year - 2006
Publication title -
chemistry – an asian journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.18
H-Index - 106
eISSN - 1861-471X
pISSN - 1861-4728
DOI - 10.1002/asia.200600076
Subject(s) - trapping , exponential distribution , exponential function , diffusion , trap (plumbing) , field (mathematics) , exponential decay , distribution (mathematics) , power law , distribution function , kinetic energy , physics , particle (ecology) , statistical physics , mathematics , mathematical analysis , classical mechanics , thermodynamics , quantum mechanics , statistics , ecology , oceanography , meteorology , pure mathematics , biology , geology
We investigate the field effect on the diffusion‐influenced reversible trapping problem in one dimension. The exact Green function for a particle undergoing diffusive motion between two static reversible traps with a constant external field is obtained. From the Green function, we derive the various survival probabilities. Two types of trap distribution for the many‐body problem are considered, the periodic and random distributions. The mean survival probability is obtained for the crossing‐forbidden case for the two types of trap distribution. For the periodic distribution it decays exponentially. For the random trap distribution, similar to the irreversible case, there exists a critical field strength at which the long time asymptotic behavior undergoes a kinetic transition from the power law to exponential behaviors. The difference between equilibrium concentrations for the two types of trap distribution due to the fluctuation effect of trap concentration vanishes as the field strength increases.