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Woodinine and its Stereomers ‐ Absolute Configuration
Author(s) -
Mahboobi Siavosh,
Burgemeister Thomas,
Wiegrebe Wolfgang
Publication year - 1993
Publication title -
archiv der pharmazie
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.468
H-Index - 61
eISSN - 1521-4184
pISSN - 0365-6233
DOI - 10.1002/ardp.19933260108
Subject(s) - diastereomer , absolute configuration , chemistry , stereochemistry , alkaloid
The synthesis of all the four stereomers of the alkaloid woodinine ( 12a ) 1) is described and the stereochemical conclusions of Païs 3) and Still 6) are discussed. The absol. configurations of woodinine ( 12a ) and its diastereomer 8b are unequivocally deduced from the pertinent piperazinediones 16 and 17 .