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Thermoresponsive nanocomposite hydrogels with high mechanical strength and toughness based on a dual crosslinking strategy
Author(s) -
Gu Heng,
Wang Gang,
Cao Xiaodong
Publication year - 2021
Publication title -
journal of applied polymer science
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.575
H-Index - 166
eISSN - 1097-4628
pISSN - 0021-8995
DOI - 10.1002/app.51509
Subject(s) - self healing hydrogels , materials science , copolymer , toughness , ultimate tensile strength , acrylate , composite material , aqueous solution , nanocomposite , polymer chemistry , chemical engineering , polymer , chemistry , organic chemistry , engineering
The practical application of thermoresponsive poly(N‐isopropylacrylamide) (PNIPAM) hydrogels are severely limited by their poor mechanical properties. Herein, we reported a series of dual crosslinked (DC) PNIPAM hydrogels with superior mechanical properties prepared by simple copolymerization of N‐isopropylacrylamide and sodium acrylate (SA) in the laponite RDS suspension, following by a soaking process in multivalent metal cations (e.g., Ca 2+ , Al 3+ , Fe 3+ ) aqueous solutions to form ionic coordination interactions with COO groups of copolymer side chains. The effect of laponite RDS, AANa (sodium acrylate), and metal cation (e.g., Fe 3+ ) concentrations on the mechanical properties and deswelling properties of the DC hydrogels are evaluated. The DC hydrogel prepared with 10 w/v% laponite RDS, 0.25 mol/L AANa and 0.45 mol/L Fe 3+ possesses the best mechanical properties (ca. 1.1 MPa of tensile strength, 9.1 MPa of compression strength at 80% of compression strain, 1.4 MPa of elastic modulus and 1.3 MJ/m 3 of toughness). Moreover, we also discovered that the DC hydrogels crosslinked by Fe 3+ showed better mechanical properties due to the larger charge and ion radius of Fe 3+ .