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Design of sandwich structure conductive polypropylene/styrene‐butadiene‐styrene triblock copolymer/carbon black composites with inherent morphological tunability
Author(s) -
Zhou Zichen,
Yang Zhangbin,
Sun Haoxuan,
Zhang Jun
Publication year - 2021
Publication title -
journal of applied polymer science
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.575
H-Index - 166
eISSN - 1097-4628
pISSN - 0021-8995
DOI - 10.1002/app.50567
Subject(s) - materials science , composite material , copolymer , carbon black , polypropylene , electrical conductor , electrical resistivity and conductivity , volume fraction , styrene butadiene , conductivity , conductive polymer , styrene , polymer , natural rubber , chemistry , electrical engineering , engineering
The insulator‐conductor transition of conductive polymer composites (CPCs) can be ascribed to the fabrication of conductive networks, and the morphology of conductive networks plays a significant role in the electrical conductivity. This study presents CPCs with inherent morphology tunability which can be controlled by kinetic methods (i.e., mixing procedures and sequences, and polymer melt viscosity). Polypropylene (PP)/styrene‐butadiene‐styrene block copolymer (SBS) (50/50, in volume)/10 phr (parts per hundred of the polymer matrix) conductive carbon black (CB) composites prepared by different compounding sequences (PP/CB composites mixed with SBS, SBS/CB composites mixed with PP, and PP/SBS blend mixed with CB) are named as PC 10 S, SC 10 P, and PSC 10 . With the difference between the phase morphologies, distribution, and dispersion of CB, the PP/SBS/CB composites realize seven orders of magnitude difference in resistivity. The volume resistivity ( ρ v ) of PC 10 S SC 10 P and PSC 10 are 1.57 × 10 1 , 1.68 × 10 2 , and 4.88 × 10 8 Ω m, respectively.