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A model to predict the solubility and permeability of gaseous penetrant in the glassy polymeric membrane at high pressure
Author(s) -
Shoghl Sibati,
Pazuki Gholamreza,
Raisi Ahmadreza
Publication year - 2021
Publication title -
journal of applied polymer science
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.575
H-Index - 166
eISSN - 1097-4628
pISSN - 0021-8995
DOI - 10.1002/app.50548
Subject(s) - penetrant (biochemical) , solubility , membrane , thermodynamics , materials science , permeation , gaseous diffusion , permeability (electromagnetism) , sorption , polymer , chemical engineering , chemistry , organic chemistry , composite material , adsorption , engineering , biochemistry , physics , electrode
In this work, the transport properties of gaseous penetrant through several dense glassy polymeric membranes are studied. The nonequilibrium lattice fluid (NELF) in conjunction with the modified Fick's law and dual mode sorption model was used to simulate the gas transport in glassy polymeric membranes. The approach is based on the sorption, diffusion, in which solubility is calculated based on the NELF model, and diffusion coefficient is obtained from the product thermodynamic coefficient and molecular mobility. The governing equation is solved by the finite element method using COMSOL multi‐physics software. The developed model for gas permeability of glassy polymeric membrane can be applied in a wide range of pressure and temperature. The comparison of the calculated permeability and solubility of gasses with the experimental data represented the ability of the developed model. Increasing feed gas temperature increases the gas permeability, while this variation leads to lower gas solubility in the glassy polymeric membranes. The effect of feed temperature and pressure on permeability and solubility is investigated, and the experimental data from literature are described by the developed model. A good prediction of the experimental data can be observed over the considered condition.