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Synthesis of stimuli‐responsive ionic cyclopolymers in search of phosphorous‐free antiscalants
Author(s) -
Yaagoob Ibrahim Y.,
Aldahdooh Mohammed K.,
AlTaq Ali A.,
AlMuallem Hasan A.,
Mazumder Mohammad A. J.,
Ali Shaikh A.
Publication year - 2021
Publication title -
journal of applied polymer science
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.575
H-Index - 166
eISSN - 1097-4628
pISSN - 0021-8995
DOI - 10.1002/app.50402
Subject(s) - ammonium persulfate , chemistry , nuclear chemistry , monomer , copolymer , ammonium , polymer , medicinal chemistry , organic chemistry
Ammonium persulfate‐initiated cyclopolymerization of maleic acid (HO 2 CC=CCO 2 H) (MA) with diallylamine (–NR 2 , R = CH 2 = CH‐CH 2 ) derivatives (DADs): R 2 NH + CH 2 CO 2 − ( I ), R 2 NCH 2 CO 2 − Na + ( II ), R 2 NCH 2 CO 2 Et ( III ), R 2 NH + (CH 2 ) 3 CO 2 − ( IV ), R 2 N(CH 2 ) 3 CO 2 Et ( V ), R 2 NH + (CH 2 ) 3 SO 3 − ( VI ) and R 2 N(CH 2 ) 3 SO 3 − Na + ( VII ) gave a series of new pH‐responsive alternate copolymers: –[(DAD‐ alt ‐MA)] n – VIII ‐ XIV , respectively. Homopolymers XV and XVI of the corresponding monomers IV and V ·HCl were also synthesized. The evaluation of the synthesized polymers as potential antiscalants in reverse osmosis (RO) plants was examined. An effective scale inhibitor must arrest the formation of scale for a residence time (≈15 min) of feed water in the RO chamber. R 2 NH + (CH 2 ) 3 CO 2 − ( IV )‐ alt ‐MA copolymer XI at a concentration of 5 ppm imparted 99% scale inhibition for 360 min, while at 2.5 and 1 ppm concentrations, the CaSO 4 scale inhibitions were found to be 99% and ≈ 100% during 120 and 20 min, respectively, at 40°C. Homopolymers XV and XVI , at a 20‐ppm concentration, demonstrated ≈ 95% efficiency in inhibiting mild steel corrosion in 1 M HCl. In some important oilfield applications, requirement of simultaneous scale and corrosion inhibition make these polymers potential candidates for desalination and oilfield applications.