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Experimental design to evaluate the efficiency of maghemite nanoparticles incorporation in styrene‐divinylbenzene copolymers
Author(s) -
Ramos Gabriela Soares Macello,
Mendes Matheus de Souza Lima,
Neves Marcia Angélica Fernandes e Silva,
Pedrosa Marcelo Sierpe,
Silva Manoel Ribeiro
Publication year - 2021
Publication title -
journal of applied polymer science
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.575
H-Index - 166
eISSN - 1097-4628
pISSN - 0021-8995
DOI - 10.1002/app.50318
Subject(s) - maghemite , divinylbenzene , copolymer , materials science , superparamagnetism , styrene , thermal stability , thermogravimetric analysis , chemical engineering , polymer , toluene , nanoparticle , polymer chemistry , magnetization , composite material , chemistry , organic chemistry , nanotechnology , magnetic field , physics , engineering , quantum mechanics
Magnetized styrene‐divinylbenzene resins can be obtained by inserting superparamagnetic nanoparticles of maghemite (γ‐Fe 2 O 3 ) in the polymeric matrix. The incorporation of this nanoparticulate material can be influenced by several factors. The objective of this work was to evaluate the influence of these variables through an experimental design, where three factors were evaluated: cross‐linking degree, initiator content and porogenic agent, at two levels. Subsequently, to evaluate the properties of the synthesized magnetized resins, magnetization curves were plotted using a vibrating sample magnetometer, thermal stability of the magnetized copolymer was determined by thermogravimetric analysis and the morphology was observed by scanning electron microscopy. The highest initiator content produced the greatest synthesis yield, and the presence of toluene had a positive effect on saturation magnetization, indicating that incorporation of maghemite in the polymer matrix and thermal degradation were influenced by higher divinylbenzene content.