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Experimental investigation of flame retardancy and mechanical properties of APP / EG / TPU multilayer composites prepared by microlayer coextrusion technology
Author(s) -
Wang Shuaiwen,
Shi Meig,
Yang Weimin,
Yan Hua,
Zhang Chao,
An Ying,
Zhang Fenghua
Publication year - 2021
Publication title -
journal of applied polymer science
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.575
H-Index - 166
eISSN - 1097-4628
pISSN - 0021-8995
DOI - 10.1002/app.50219
Subject(s) - materials science , thermoplastic polyurethane , composite material , ammonium polyphosphate , ultimate tensile strength , polyurethane , thermal stability , dispersion (optics) , combustion , fire retardant , chemical engineering , elastomer , chemistry , physics , optics , organic chemistry , engineering
Abstract In this paper, ammonium polyphosphate(APP)/expandable graphite(EG)/thermoplastic polyurethane (TPU) composites were prepared by microlayer coextrusion technology, APP and EG fillers had good synergistic flame retardancy and excellent dispersion in TPU matrix, which greatly improved the flame retardancy and mechanical properties of multilayer composites. The dispersion of APP and EG in TPU was characterized by using SEM, the flame retardancy of composites was characterized by using UL94 and LOI, the thermal stability of composites was characterized by using TGA and DTG, and tensile test was used to characterized the mechanical properties of composites. SEM showed that the microlayer coextrusion technology significantly improved the dispersion of APP and EG in TPU. As showed by the experimental results, the vertical combustion level of ordinary blended composites reached V‐2 after adding only one kind of filler either APP or EG, and the vertical combustion level of ordinary blended composites reached V‐0 with APP and EG applied together, while the vertical combustion level of microlayer coextruded composites all reached V‐0 when the total addition of APP and EG was 15%. In particular, the LOI value of microlayer coextruded composites was 30.9%, while the LOI value of ordinary blended composites only was 27.9% when APP: EG = 1: 1. At this time, the flame retardancy level of APP/EG/TPU composites was the best. In addition, the thermal stability and mechanical properties of microlayer coextruded composites were far superior to ordinary blended composites. In conclusion, the synergistic flame retardancy of APP and EG fillers and the dispersion of APP and EG fillers in TPU matrix played a significant role in enhancing flame retardancy and mechanical properties.