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Poly(acrylic acid)/poly(acrylamide) hydrogel adsorbent for removing methylene blue
Author(s) -
Lv Qingyun,
Shen Yong,
Qiu Yu,
Wu Min,
Wang Liming
Publication year - 2020
Publication title -
journal of applied polymer science
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.575
H-Index - 166
eISSN - 1097-4628
pISSN - 0021-8995
DOI - 10.1002/app.49322
Subject(s) - adsorption , acrylic acid , methylene blue , monomer , acrylamide , langmuir adsorption model , self healing hydrogels , cationic polymerization , copolymer , polymer chemistry , chemical engineering , chemistry , acid dye , materials science , nuclear chemistry , polymer , organic chemistry , dyeing , catalysis , photocatalysis , engineering
Cationic dye can cause severe damage to the environment due to their refractory degradation, complex composition and strong stability. Hydrogels as adsorbents have been widely used to treatment the wastewater with dyestuff for their low prices, simple operations, and high efficiency. This work uses poly(acrylic acid) (PAA)/poly(acrylamide)(PAM)/calcium hydroxide nanoparticles (CHN) polymeric hydrogel absorbent to eliminate methylene blue (MB) dye. First, PAM/PAA/CHN hydrogel is produced through copolymerization of acrylic acid monomer and acrylamide monomer using inorganic CHN as cross‐linker. And then, the adsorption performance of such PAM/PAA/CHN hydrogel adsorbent for adsorbing MB dye is explored at different conditions including pH, contacting time, adsorbent dosage, initial concentration of MB, and temperature. A maximum adsorption capability for adsorbing MB reaches 1,056 mg/g. Furthermore, the pseudo‐first‐order mode and Langmuir isotherm model can well describe adsorption behavior of MB dye onto such PAA/PAM/CHN hydrogel adsorbent. Thereby, as‐prepared PAA/PAM/CHN hydrogel could be a potential adsorbent for eliminating organic dyes from wastewater.