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Plasma‐modified CNFs, GPs, and their mixtures for enhanced polypropylene thermal conductivity
Author(s) -
CovarrubiasGordillo Carlos Andrés,
SorianoCorral Florentino,
ÁvilaOrta Carlos Alberto,
FonsecaFlorido Heidi Andrea,
GonzálezMorones Pablo,
CruzDelgado Víctor Javier,
CabelloAlvarado Christian Javier
Publication year - 2020
Publication title -
journal of applied polymer science
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.575
H-Index - 166
eISSN - 1097-4628
pISSN - 0021-8995
DOI - 10.1002/app.49138
Subject(s) - materials science , scanning electron microscope , polypropylene , thermal conductivity , conductivity , chemical engineering , raman spectroscopy , transmission electron microscopy , analytical chemistry (journal) , composite material , nanotechnology , chemistry , chromatography , optics , physics , engineering
Low thermal conductivity of polypropylene (PP) is a key factor in limiting its use for the manufacture of solar heaters. To overcome this problem, in the present work, two different methods were tested to increase the thermal conductivity of a PP matrix by increasing the dispersion and compatibility between PP and carbon nanoparticles (CNPs). In the first method, CNPs modified superficially by plasma of propylene were used, and in the second, mixtures of CNPs (carbon nanofibers and graphene platelets in 9:1, 8:2, and 7:3 ratios) were used. Dispersion and compatibility between PP and CNPs were tested by scanning electron microscopy (SEM), transmission electron microscopy (TEM) and Raman spectroscopy. The results show that both methodologies increase the dispersion and compatibility and, therefore, the thermal conductivity of the PP matrix (0.14 W m −1 K −1 ), which reached up 0.90 W m −1 K −1 . It was also observed that dispersion is a key factor in high concentrations (5 wt/wt%) of CNPs to obtain high thermal conductivity and compatibility in low concentrations (1 wt/wt%). Finally, only a synergistic effect was observed at 1 wt/wt% when using surface‐modified CNPs by plasma and at 5 wt/wt% when the CNPs were used without surface treatment.