z-logo
Premium
Mechanical, thermal, and structural properties of uniaxially drawn polylactic acid/halloysite nanocomposites
Author(s) -
Bagheri Ehsan,
Mosaddegh Peiman,
Behzad Tayebeh
Publication year - 2020
Publication title -
journal of applied polymer science
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.575
H-Index - 166
eISSN - 1097-4628
pISSN - 0021-8995
DOI - 10.1002/app.49134
Subject(s) - materials science , polylactic acid , composite material , crystallinity , ultimate tensile strength , halloysite , nanocomposite , toughness , composite number , dynamic mechanical analysis , compression molding , scanning electron microscope , glass transition , polymer , mold
The effect of solid‐state drawing at different conditions including drawing ratio (DR), drawing temperature (DT), and drawing speed (DS) on mechanical, thermal, and structural properties of polylactic acid (PLA)/halloysite nanotubes (HNTs) composites were studied. PLA/HNTs composite films were prepared by melt mixing process followed by compression molding. Subsequently, drawing was performed using a tensile testing machine. Field emission scanning electron microscopy confirmed alignment and orientation of polymer chains and HNTs after stretching. Thermal and mechanical analysis of the drawn films revealed that glass transition temperature, crystallinity, ultimate tensile strength, and Young's modulus were enhanced by increasing DR, DT, and DS. However, toughness was decreased by increasing DR and DS and increased by increasing DT. In addition, the drawn nanocomposites showed superior mechanical and thermal properties compared to the drawn neat PLA films indicating the high efficiency of solid‐state drawing and positive effect of HNTs. Therefore, this study could be helpful to introduce an approach to enhance the properties of biopolymers and renewable polymers by uniaxial drawing.

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here