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Acrylic acid/allyloxy polyethylene glycol copolymer with methoxysilicon end groups as a highly effective dispersant for nano‐SiO 2 aqueous system
Author(s) -
Yang Bing,
Zhou Yu,
Chen Hongxiang,
Zhang Song,
Liu Jingyi
Publication year - 2020
Publication title -
journal of applied polymer science
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.575
H-Index - 166
eISSN - 1097-4628
pISSN - 0021-8995
DOI - 10.1002/app.48617
Subject(s) - dispersant , dispersity , copolymer , polyethylene glycol , aqueous solution , materials science , acrylic acid , polymer chemistry , chemical engineering , zeta potential , nanoparticle , organic chemistry , dispersion (optics) , chemistry , polymer , nanotechnology , composite material , physics , optics , engineering
In order to improve the dispersity and stability of nano‐SiO 2 aqueous system with high solid content, acrylic acid/allyloxy polyethylene glycol copolymer dispersants with methoxysilicon end groups (KH590‐AA x ‐APEG y ) were synthesized by photopolymerization. After adding KH590‐AA x ‐APEG y into the nano‐SiO 2 aqueous system, the viscosity, the curing time, the particle size, and the zeta potential of these systems were respectively measured. The results showed that introducing polyethylene glycol chain into the dispersant was beneficial to better exerting its electrostatic repulsion and steric hindrance effects and further improving the dispersibility of the nano‐SiO 2 aqueous system. Moreover, the dispersion stability of SiO 2 nanoparticles in water was closely related to the composition, the molecular weight, and the addition amount of KH590‐AA x ‐APEG y and the solid content. When the molecular weight of KH590‐AA x ‐APEG y was 3200 g mol −1 and its addition amount was 0.1 wt %, the nano‐SiO 2 aqueous system with 20 wt % solid content showed the best dispersity and stability. © 2019 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2020 , 137 , 48617.