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Novel thin‐film nanocomposite membrane with water‐soluble polyhydroxylated fullerene for the separation of Mg 2+ /Li + aqueous solution
Author(s) -
Shen Qian,
Xu SunJie,
Xu ZhenLiang,
Zhang HaiZhen,
Dong ZheQin
Publication year - 2019
Publication title -
journal of applied polymer science
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.575
H-Index - 166
eISSN - 1097-4628
pISSN - 0021-8995
DOI - 10.1002/app.48029
Subject(s) - membrane , aqueous solution , nanofiltration , nanocomposite , chemical engineering , interfacial polymerization , contact angle , x ray photoelectron spectroscopy , fullerene , materials science , chemistry , analytical chemistry (journal) , polymer chemistry , nuclear chemistry , chromatography , polymer , organic chemistry , nanotechnology , monomer , biochemistry , engineering
ABSTRACT Despite the prosperity of membrane technology, the separation efficiency for Mg 2+ /Li + mixture is still far from satisfactory. Herein, a novel thin‐film nanocomposite (TFN) membrane was developed by loading polyhydroxylated fullerene (PHF) via interfacial polymerization. The effects of the PHF dosages on the as‐developed membranes were investigated comprehensively by XPS, SEM, AFM, contact angle measurements, as well as nanofiltration tests. The results revealed the TFN membrane containing 0.01% (w/v) PHF exhibited the optimum performances. The membrane showed a pure water flux of 6.7 L·m −2 ·h −1 ·bar −1 and salt rejections with the order of Na 2 SO 4 (95.6%) > MgSO 4 (93.6%) > MgCl 2 (89.9%) > NaCl (22.6%) > LiCl (16.3%). The membrane not only presented a separation factor of 13.1 in separating Mg 2+ /Li + mixtures, but also demonstrated excellent antifouling ability, which enables membrane regeneration without operation break, suggesting its great potentials in the recovery of Li + from brine or seawater. © 2019 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2019 , 136 , 48029.