Premium
Water‐swellable, tough, and stretchable inorganic–organic sulfoaluminate cement/polyacrylamide double‐network hydrogel composites
Author(s) -
Chu Y. Y.,
Song X. F.,
Zhao H. X.
Publication year - 2019
Publication title -
journal of applied polymer science
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.575
H-Index - 166
eISSN - 1097-4628
pISSN - 0021-8995
DOI - 10.1002/app.47905
Subject(s) - materials science , polyacrylamide , composite material , self healing hydrogels , swelling , composite number , ultimate tensile strength , compressive strength , brittleness , thermal stability , polymerization , cement , polymer , chemical engineering , polymer chemistry , engineering
Effectively improving the mechanical properties of the hydrogel can greatly broaden its application range. The design concept of forming a double‐network structure by organic–inorganic hybridization can greatly enhance the mechanical properties of traditional hydrogels. Here, a series of organic–inorganic double‐network (OIDN) polyacrylamide/(sulfoaluminate cement) (PAM/SAC) composite gels by solution polymerization were synthesized at room temperature. The OIDN composite gels not only retain the characteristics of water swelling but also exhibit excellent tensile properties (stress and strain are 12 MPa and 2500%, respectively) and compressive strength (stress and strain are 65 MPa and 80%, respectively). In the preparation process, a brittle inorganic network of hydrated sulfoaluminate (hydra‐SAC) and a ductile network of polyacrylamide (PAM) were formed by the manner of interpenetrating. The phase composition and thermal stability of the OIDN composite gels were characterized and determined by FTIR, XRD, SEM, and TGA, respectively. The effect of SAC on swelling and mechanical performance of the OIDN composite gels was also investigated. The results show that the use of SAC hybrid hydrogels can effectively improve the mechanical strength, and the OIDN composite gels are expected to be a potential grouting and plugging functional material. © 2019 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2019 , 136 , 47905.