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Improvement of carbon nanotube dispersion in electrospun polyacrylonitrile fiber through plasma surface modification
Author(s) -
Gürsoy Mehmet,
Özcan Fatih,
Karaman Mustafa
Publication year - 2019
Publication title -
journal of applied polymer science
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.575
H-Index - 166
eISSN - 1097-4628
pISSN - 0021-8995
DOI - 10.1002/app.47768
Subject(s) - polyacrylonitrile , materials science , carbon nanotube , wetting , contact angle , polymer , surface modification , composite material , fiber , composite number , chemical vapor deposition , dispersion (optics) , acrylate , chemical engineering , nanotechnology , copolymer , physics , optics , engineering
In this study, surfaces of multiwalled carbon nanotubes (CNTs) were functionalized with poly(hexafluorobutyl acrylate) (PHFBA) thin film using a rotating‐bed plasma‐enhanced chemical vapor deposition (PECVD) method without imparting any defects on their surfaces. Polyacrylonitrile (PAN) electrospun polymer fiber mats and composite fiber mats with CNTs and functionalized CNTs ( f ‐CNTs) were prepared. The wettability and chemical and morphological properties of the synthesized fiber mats were investigated, and the dispersion of CNTs and f ‐CNTs in the polymer matrix was compared according to the contact angle results of electrospun polymer mats. According to the chemical and morphological characterization results, PHFBA‐coated CNTs were dispersed more uniformly in the polymer matrix than the uncoated CNTs. The f ‐CNTs/PAN composite fiber mat exhibits a lower surface energy than the pristine CNTs/PAN fiber mat. © 2019 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2019 , 136 , 47768.