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Effect of the nanoparticles in the stability of hydrolyzed polyacrylamide/resorcinol/formaldehyde gel systems for water shut‐off/conformance control applications
Author(s) -
PérezRobles Saray,
Cortés Farid B.,
Franco Camilo A.
Publication year - 2019
Publication title -
journal of applied polymer science
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.575
H-Index - 166
eISSN - 1097-4628
pISSN - 0021-8995
DOI - 10.1002/app.47568
Subject(s) - syneresis , nanoparticle , chemical engineering , resorcinol , materials science , polyacrylamide , hydrolysis , formaldehyde , zeta potential , chemistry , polymer chemistry , nanotechnology , organic chemistry , engineering
The main objective of this work is to evaluate the inclusion of nanoparticles to partially hydrolyzed polyacrylamide/resorcinol/formaldehyde gel systems to improve the stability under static and dynamic conditions. Oxide nanoparticles (<100 mg·L −1 ) of SiO 2 , Al 2 O 3 , MgO, and Cr 2 O 3 were employed and characterized by their physicochemical properties. Gels were prepared and subsequently placed at 70 °C for evaluating the nanoparticles influence in gel strength through rheological properties and syneresis measurements. Al 2 O 3 nanoparticles showed the highest potential for the reduction of the syneresis phenomena, followed by MgO and Cr 2 O 3 . The SiO 2 nanoparticles lead to a higher degradation of the gel. As the zeta potential increases, the syneresis of the gel system decreases. The nanoparticles did not significantly affect the storage modulus, describing similar gel strength than the original gel. Also, displacement tests showed an incremental of 64% of oil recovery regarding the system in the absence of Al 2 O 3 nanoparticles. © 2019 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2019 , 136 , 47568.