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Thermokinetics study of degradation process of soybean‐based polyurethane foams
Author(s) -
Zhou Xinxing
Publication year - 2019
Publication title -
journal of applied polymer science
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.575
H-Index - 166
eISSN - 1097-4628
pISSN - 0021-8995
DOI - 10.1002/app.47357
Subject(s) - thermogravimetry , polyurethane , soybean oil , degradation (telecommunications) , differential scanning calorimetry , activation energy , thermal stability , materials science , fourier transform infrared spectroscopy , kinetics , nuclear chemistry , chemical engineering , chemistry , composite material , organic chemistry , biochemistry , thermodynamics , telecommunications , physics , quantum mechanics , computer science , engineering
Polyurethane (PU) production with the use of soybean oil was greatly appreciated by researchers due to their low cost, easy availability, and nontoxic nature. The thermokinetics and degradation process of soybean oil‐based PU (SPU) were measured by differential scanning calorimetry–thermogravimetry–Fourier transform infrared spectrum. Influence of various factors such as the NCO/OH molar ratio (1.5–2.0) and different heating rates on the thermodynamic properties and thermal stability during the degradation process were studied in detail. Moreover, the thermokinetics mechanism included activation energy, reaction rate, and kinetic parameters of the degradation process were evaluated using “AKTS‐Thermokinetics” software. The reaction rate ranged from 0.0005 to 0.0025 at the first stage (60–150 °C), then changed to values between 0.00025 and 0.0015 at the second stage (250–350 °C) and between 0.00025 and 0.0020 at the third stage (400–550 °C). It was observed that the degradation progress included with three‐ or four‐step degradation profiles. As the soybean oil content or NCO/OH molar ratio increase, the thermal stability of SPU increased. In addition, the activation energy and reaction rate increased with the increased soybean oil contents. © 2018 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2019 , 136 , 47357.