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Characterization and property investigation of novel eco‐friendly agar/carrageenan/TiO 2 nanocomposite films
Author(s) -
Hou X.,
Xue Z.,
Liu J.,
Yan M.,
Xia Y.,
Ma Z.
Publication year - 2019
Publication title -
journal of applied polymer science
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.575
H-Index - 166
eISSN - 1097-4628
pISSN - 0021-8995
DOI - 10.1002/app.47113
Subject(s) - nanocomposite , materials science , nano , ultimate tensile strength , chemical engineering , molecule , solubility , elongation , composite material , polymer chemistry , chemistry , organic chemistry , engineering
Agar/kappa carrageenan (AG/CA) nanocomposite films are prepared using thermal casting method in the presence of various concentrations of nano‐TiO 2 (0.5, 1, 1.5, and 2 g/100 g). As nano‐TiO 2 content rises from 0 to 1 g/100 g, tensile strength (TS) increases from 30.8 to 60.6 MPa. However, TS decreases gradually as nano‐TiO 2 content further raises. TS of films containing 1 g/100 g nano‐TiO 2 increases by 96.8% when compared to those prepared without nano‐TiO 2 . The reason may be related to the formation of intermolecular hydrogen bonding and coordinate bonds between nano‐TiO 2 and matrix molecules. Elongation at break decreases gradually as nano‐TiO 2 concentration increases. The addition of nano‐TiO 2 improves barrier properties of films against ultraviolet light, while it decreases their transparency. Swelling and water solubility of the films containing 1 g/100 g nano‐TiO 2 decrease, further demonstrating that interaction forces are formed between nano‐TiO 2 and matrix molecules. The addition of nano‐TiO 2 significantly declines water vapor permeability. Overall, films containing 1 g/100 g nano‐TiO 2 show the best mechanical, optical, and water resistance properties. © 2018 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2019 , 136 , 47113.