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Correlation between morphology and electrical breakdown strength of the polypropylene/maleic anhydride grafted polypropylene/nano‐ZrO 2 ternary system
Author(s) -
Liu Wenfeng,
Cheng Lu,
Liu Xiaowei,
Liu Chengming,
Chi Xiaohong,
Li Shengtao
Publication year - 2018
Publication title -
journal of applied polymer science
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.575
H-Index - 166
eISSN - 1097-4628
pISSN - 0021-8995
DOI - 10.1002/app.46842
Subject(s) - maleic anhydride , polypropylene , materials science , ternary operation , nano , dispersion (optics) , ternary numeral system , morphology (biology) , nanoparticle , copolymer , tacticity , chemical engineering , polymer chemistry , composite material , polymer , nanotechnology , polymerization , physics , engineering , biology , computer science , optics , genetics , programming language
A ternary system composed of isotactic polypropylene (PP), maleic anhydride grafted polypropylene (PP‐g‐MAH), and nano‐ZrO 2 was designed. To investigate the influence of each composition, we systematically designed orthogonal tests with 25 samples with various PP‐g‐MAH (0–70 wt %) and nano‐ZrO 2 concentrations (0–5 wt %). Microscopic observation showed that the introduction of PP‐g‐MAH could distinctively benefit the dispersion of nanoparticles. This can be understood by chemical bonds between PP‐g‐MAH and the nano‐ZrO 2 surface, which was evidenced by infrared spectroscopy. Meanwhile, both the crystalline properties and aggregation structures were improved within this ternary system. Macroscopically, a great enhancement of DC breakdown strength (BDS) as high as 43.3% was achieved when the PP‐g‐MAH concentration was 50 wt % and the nano‐ZrO 2 concentration was 0.5 wt %. Moreover, the effects of PP‐g‐MAH and nano‐ZrO 2 were revealed respectively. The increase of nano‐ZrO 2 content could cause the first increase and then decrease of BDS. The influence of PP‐g‐MAH on breakdown strength was obviously shown by the analysis of variance, and the rising PP‐g‐MAH concentration could lead to the nano‐ZrO 2 content with the highest BDS shifted to higher loading, indicating that the modified dispersion of nanoparticles played the dominant role in the breakdown performance improvement. © 2018 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2018 , 135 , 46842.