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Mechanical and piezo‐resistive properties of styrene–butadiene–styrene copolymer covalently modified with graphene/styrene–butadiene–styrene composites
Author(s) -
Hong Kailiang,
Wang Zhe,
Lu Guoming,
Wei Lai,
Yuan Zhijuan,
Wang Hongqing,
Qiao Zhen,
Wang Lun,
Wang Xue,
Li Zewen
Publication year - 2018
Publication title -
journal of applied polymer science
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.575
H-Index - 166
eISSN - 1097-4628
pISSN - 0021-8995
DOI - 10.1002/app.46568
Subject(s) - materials science , graphene , composite material , copolymer , styrene butadiene , styrene , maleic anhydride , polymer chemistry , polymer , nanotechnology
As novel piezoelectric materials, carbon‐reinforced polymer composites exhibit excellent piezoelectric properties and flexibility. In this study, we used a styrene–butadiene–styrene triblock copolymer covalently grafted with graphene (SBS‐ g ‐RGO) to prepare SBS‐ g ‐RGO/styrene–butadiene–styrene (SBS) composites to enhance the organic solubility of graphene sheets and its dispersion in composites. Once exfoliated from natural graphite, graphene oxide was chemically modified with 1,6‐hexanediamine to functionalize with amino groups (GO–NH 2 ), and this was followed by reduction with hydrazine [amine‐functionalized graphene oxide (RGO–NH 2 )]. SBS‐ g ‐RGO was finally obtained by the reaction of RGO–NH 2 and maleic anhydride grafted SBS. After that, X‐ray diffraction, X‐ray photoelectron spectroscopy, Raman spectroscopy, scanning electron microscopy, transmission electron microscopy, thermogravimetric analysis, and other methods were applied to characterize SBS‐ g ‐RGO. The results indicate that the SBS molecules were grafted onto the graphene sheets by covalent bonds, and SBS‐ g ‐RGO was dispersed well. In addition, the mechanical and electrical conductivity properties of the SBS‐ g ‐RGO/SBS composites showed significant improvements because of the excellent interfacial interactions and homogeneous dispersion of SBS‐ g ‐RGO in SBS. Moreover, the composites exhibited remarkable piezo resistivity under vertical compression and great repeatability after 10 compression cycles; thus, the composites have the potential to be applied in sensor production. © 2018 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2018 , 135 , 46568.