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Preparation, analysis, and isothermal crystallization behavior of poly[1,3‐bis(aminomethyl)cyclohexamethylene oxamide]
Author(s) -
Mutua Fredrick Nzioka,
Yang Tingting,
Gao Yuanbo,
Zhu Bo,
He Yong
Publication year - 2018
Publication title -
journal of applied polymer science
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.575
H-Index - 166
eISSN - 1097-4628
pISSN - 0021-8995
DOI - 10.1002/app.46345
Subject(s) - materials science , crystallinity , thermal stability , crystallization , polymer chemistry , fourier transform infrared spectroscopy , glass transition , chemical engineering , polymer , composite material , engineering
Poly[1,3‐bis(aminomethyl)cyclohexaneoxamide] (PBAC2) was synthesized using 1,3‐bis(aminomethyl)cyclohexane (BAC) and dibutyl oxalate (DO) via spray/solid‐state polycondensation (SSP). The structure of the synthesized polyoxamide was confirmed by 1 H‐nuclear magnetic resonance (NMR) and Fourier transform infrared spectroscopy. The weight average molecular weight ( M w ) of the polyoxamides prepared was 1.35 × 10 5 . The polyoxamides showed excellent thermal properties with glass transition temperature ( T g ) of 150 °C, melting temperature ( T m ) of 318 °C, crystallization temperature( T c ) of 253 °C, and initial degradation temperature ( T d ) of 417 °C suggesting higher thermal stability than commercial polyamide 6 ( T d = 378 °C). Kinetic studies of PBAC2 predicted a two‐dimensional crystal growth. X‐ray diffraction powder diffraction suggested that the polymer has high crystallinity. A saturated water absorption of 2.8 wt % was recorded for the new polyoxamide, giving it a competitive edge for applications in civil aviation, reinforced plastics, and electronics industry where precise dimensional stability and high thermal resistance properties are a priority. © 2018 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2018 , 135 , 46345.