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Recyclable bio‐based crosslinked polyurethanes with self‐healing ability
Author(s) -
Gu Lin,
Wu QingYun
Publication year - 2018
Publication title -
journal of applied polymer science
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.575
H-Index - 166
eISSN - 1097-4628
pISSN - 0021-8995
DOI - 10.1002/app.46272
Subject(s) - materials science , ultimate tensile strength , polyurethane , compression molding , differential scanning calorimetry , composite material , shore durometer , extender , elongation , polymer , molding (decorative) , copolymer , polymer chemistry , mold , physics , thermodynamics
ABSTRACT We report the synthesis of a linear bio‐based polyurethane (bio‐PU) containing furan ring by using renewable polylactide copolymer diol and 2,5‐furandimethanol as a soft segment and chain extender, respectively, in which the reversible crosslinked covalent bonds between hard segments were incorporated via Diels–Alder (D‐A) reaction between the furan ring of the chain extender and bismaleimide (BM) crosslinker. By simply controlling the amount of BM, mechanical properties of the obtained crosslinked bio‐PUs (CBPUs) were varied widely. In particular, the CBPU100 sample shows the highest tensile strength of 10.8 MPa, Young's modulus of 193 MPa, and an elongation of 155%. The differential scanning calorimetry experiments verify the recycle property of the CBPUs by the D‐A/retro‐D‐A reaction at the proper temperature. The thermal recyclability and remolding ability of these materials are demonstrated by two kinds of polymer processing methods, i.e., solution casting and hot‐compression molding. The recycled CBPUs display almost identical elongation and slightly decreased tensile strength compared to the as‐synthesized samples. Furthermore, the CBPUs also exhibit excellent self‐healing ability. Therefore, the resulting CBPUs possess tunable mechanical properties, good thermal recyclability, re‐mending, and self‐healing ability, which makes the bio‐based materials more eco‐friendly. © 2018 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2018 , 135 , 46272.