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Fabrication of novel polyaniline/flowerlike copper monosulfide composites with enhanced electromagnetic interference shielding effectiveness
Author(s) -
Hu XiaoSai,
Shen Yong
Publication year - 2017
Publication title -
journal of applied polymer science
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.575
H-Index - 166
eISSN - 1097-4628
pISSN - 0021-8995
DOI - 10.1002/app.45232
Subject(s) - polyaniline , materials science , electromagnetic shielding , composite material , thermogravimetric analysis , in situ polymerization , scanning electron microscope , fourier transform infrared spectroscopy , conductive polymer , polymerization , electromagnetic interference , polymer , chemical engineering , electronic engineering , engineering
Novel polyaniline (PANI)/flowerlike CuS composites with improved electromagnetic interference (EMI) shielding effectiveness (SE) were prepared through the in situ polymerization of PANI into the flowerlike CuS microspheres. X‐ray diffraction, scanning electron microscopy, Fourier transform infrared spectroscopy, ultraviolet–visible optical absorption spectroscopy, thermogravimetric analysis, electrical conductivity testing, and EMI SE testing were used to characterize the as‐obtained products. The results reveal that the flowerlike CuS was uniformly coated by a PANI shell. Most importantly, compared with the original CuS and pure PANI, the novel PANI/flowerlike CuS composites exhibited a remarkably enhanced SE. With a thickness of 3 mm, the optimal EMI SE of the PANI–CuS composites reached −45.2 dB at 2.78 GHz, and an improved shielding efficiency below −18 dB was also obtained over the frequency range from 300 kHz to 3 GHz. This suggested that these novel PANI/flowerlike CuS composites have promising applications in the field of shielding materials. © 2017 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2017 , 134 , 45232.