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New polyurea MWCNT s nanocomposite films with enhanced mechanical properties
Author(s) -
Toader Gabriela,
Rusen Edina,
Teodorescu Mircea,
Diacon Aurel,
Stanescu Paul O.,
Damian Celina,
Rotariu Traian,
Rotariu Adrian
Publication year - 2017
Publication title -
journal of applied polymer science
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.575
H-Index - 166
eISSN - 1097-4628
pISSN - 0021-8995
DOI - 10.1002/app.45061
Subject(s) - polyurea , thermogravimetric analysis , nanocomposite , materials science , differential scanning calorimetry , dynamic mechanical analysis , composite material , carbon nanotube , epoxy , scanning electron microscope , surface modification , thermal stability , ultimate tensile strength , raman spectroscopy , x ray photoelectron spectroscopy , chemical engineering , polymer , polyurethane , physics , optics , engineering , thermodynamics
Polyurea nanocomposites represent a promising option in the development of advanced materials for applications that require high mechanical resistance. This article describes an optimized synthetic route for obtaining polyurea nanocomposites with enhanced mechanical properties by employing epoxy‐functionalized multiwalled carbon nanotubes (MWCNTs) as reinforcing agent. The experimental measurements revealed that these functionalized nanofillers have a positive effect on the properties of the composite only until they reach a certain concentration; therefore, the optimal composition was reported (the samples containing 0.2 weight % functionalized MWCNTs). The functionalization of the MWCNTs was confirmed through RAMAN, X‐ray photoelectron spectroscopy, scanning electron microscopy and thermogravimetric analysis, while the polyurea nanocomposites obtained have been characterized by thermal (differential scanning calorimetry and TGA) and mechanical (dynamic mechanical analysis and tensile tests) analyses. © 2017 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2017 , 134 , 45061.