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Orthogonal design preparation of phenolic fiber by melt electrospinning
Author(s) -
Xie Gai,
Chen Zhiyuan,
Ramakrishna Seeram,
Liu Yong
Publication year - 2015
Publication title -
journal of applied polymer science
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.575
H-Index - 166
eISSN - 1097-4628
pISSN - 0021-8995
DOI - 10.1002/app.42574
Subject(s) - electrospinning , materials science , fiber , polymer science , composite material , synthetic fiber , chemical engineering , polymer chemistry , polymer , engineering
ABSTRACT Through orthogonal experimental methods, the melt electrospinning of pure phenolic fibers has been achieved. The preparation is based on an orthogonal experimental method, which was designed to investigate the optimal conditions for production through integrated effects of spinning temperature, gap between spinneret and collector, as well as applied voltage. We found that optimal spinning conditions at 160°C, a spinneret‐to‐collector gap of 8 cm, and applied voltage at 40 kV produce an average electrospun fiber diameter reaching 4.44 ± 0.76 μm, with narrow variance distribution. The fibers were cured in a solution with 18.5% formaldehyde and 12% hydrochloric acid, heated from room temperature to 80°C and maintained 1h. In this report, the morphology, structural changes, and heat resistance of the fibers are characterized. Obtained results reveal that curing the fiber reduces crystallization and improves heat resistance. © 2015 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2015 , 132 , 42574.