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Altering the viscosity of cationically modified cellulose polymers by the addition of salt
Author(s) -
Donnelly Marc W.,
Hailemichael Mahilet,
Liberatore Matthew W.
Publication year - 2015
Publication title -
journal of applied polymer science
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.575
H-Index - 166
eISSN - 1097-4628
pISSN - 0021-8995
DOI - 10.1002/app.41616
Subject(s) - viscosity , salt (chemistry) , polymer , shear thinning , reduced viscosity , shear rate , cellulose , intrinsic viscosity , rheology , relative viscosity , chemistry , apparent viscosity , polymer chemistry , materials science , chemical engineering , thermodynamics , organic chemistry , composite material , physics , engineering
The concentration dependence of viscosity is examined for four cationically modified cellulose polymers (UCARE™ JR400, UCARE™ JR30M, UCARE™ LR400, and UCARE™ LR30M) in both salt‐free and 50 m M NaCl solution. Similarities in the four polymer systems include: Newtonian viscosity in the dilute regime, shear thinning at higher concentrations, four concentration regimes in salt‐free solution, and three concentration regimes in salt solution. The zero shear rate viscosity and the degree of shear thinning increase with increasing polymer concentration in both salt and salt‐free solutions. While the addition of salt to the lower molecular weight polymers JR400 and LR400 resulted in small changes in viscosity across all concentrations, JR30M and LR30M exhibited significant decreases (up to 81%) and increases (up to 57%) in viscosity upon the addition of salt in the semidilute and entangled regimes, respectively. This viscosity increase in the entangled regime (when comparing salt‐free and 50 mM NaCl solutions) is reported for the first time in cationically modified cellulose polymers. © 2014 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2015 , 132 , 41616.