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Cellulose nanocrystal driven crystallization of poly( d , l ‐lactide) and improvement of the thermomechanical properties
Author(s) -
CamareroEspinosa Sandra,
Boday Dylan J.,
Weder Christoph,
Foster E. Johan
Publication year - 2015
Publication title -
journal of applied polymer science
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.575
H-Index - 166
eISSN - 1097-4628
pISSN - 0021-8995
DOI - 10.1002/app.41607
Subject(s) - materials science , crystallization , differential scanning calorimetry , dynamic mechanical analysis , chemical engineering , nanocrystal , lactide , amorphous solid , lamellar structure , polymer , composite material , thermal stability , copolymer , chemistry , nanotechnology , crystallography , thermodynamics , physics , engineering
The technological exploitation of polylactide in fields requiring wide range of operating conditions is limited by the low crystallization rate of the polymer and therewith the low thermomechanical stability. Here we report the crystallization and consequent improvement of the thermomechanical properties of originally amorphous poly( d,l ‐lactide) ( d : l ratio 11 : 89) loaded with cellulose nanocrystals (CNCs). Isothermal treatment of samples with different CNC contents and at various temperatures, showed up to 6 wt % crystalline phase formation, as confirmed by differential scanning calorimetry and X‐ray diffraction measurements. Under a particular set of annealing conditions, CNCs promote the formation of a lamellar structure. This provides the system with higher order and cohesion which in combination with stress‐transfer between CNCs, led to an increase of the storage modulus in the rubbery plateau up to 30 times (from 2.7 MPa up to 79 MPa), a rise of the melting temperature up to 50°C, and an improvement of the Young's modulus up to 40%. © 2014 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2015 , 132 , 41607.