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Fluorene‐based click polymers: Relationship between molecular structure and nonlinear optical properties
Author(s) -
Ji Xiaoli,
Guang Shanyi,
Xu Hongyao,
Ke Fuyou,
Qin Xiaoyun
Publication year - 2014
Publication title -
journal of applied polymer science
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.575
H-Index - 166
eISSN - 1097-4628
pISSN - 0021-8995
DOI - 10.1002/app.40878
Subject(s) - fluorene , polymer , chromophore , materials science , thermal stability , click chemistry , conjugated system , thermogravimetric analysis , polymer chemistry , side chain , spectroscopy , fourier transform infrared spectroscopy , chemical engineering , photochemistry , chemistry , organic chemistry , composite material , physics , quantum mechanics , engineering
To further understand the relationship between the polymer structure and nonlinear optical (NLO) property, in this article, three fluorene‐based triazole functional polymers with different linked chains were designed and controllably prepared by click chemistry method. The structures and properties of these polymers were characterized and evaluated with Fourier transform infrared spectroscopy, nuclear magnetic resonance spectroscopy, ultraviolet spectroscopy, fluorescence spectra, dynamic state laser light scattering, thermogravimetric analysis, and NLO analyses. The results exhibited that the target polymers displayed good solubility, high thermal stability, and well NLO properties. The relationships between molecular structures and optical properties were investigated by both theoretical simulation and experimental results. It was found that the rigid conjugated linked chain between triazole and chromophore can effectively enhance the NLO properties of the resultant polymers. The suitable rigid and flexible groups in the triazole polymers will result in good thermal stabilities. © 2014 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2014 , 131 , 40878.