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Dielectric properties of C 60 and Sc 3 N@C 80 fullerenol containing polyurethane nanocomposites
Author(s) -
Ahmed Hanaa M.,
Hassan Mohammad K.,
Mauritz Kenneth A.,
Bunkley Steven L.,
Buchanan Randy K.,
Buchanan J. Paige
Publication year - 2014
Publication title -
journal of applied polymer science
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.575
H-Index - 166
eISSN - 1097-4628
pISSN - 0021-8995
DOI - 10.1002/app.40577
Subject(s) - fullerene , materials science , nanocomposite , dielectric , polyurethane , polymer , analytical chemistry (journal) , polymer chemistry , composite material , chemistry , organic chemistry , optoelectronics
Polymer–fullerene nanocomposites consisting of linear polyurethane (PU) chains crosslinked via increasing loadings of polyhydroxylated fullerenes (C 60 and Sc 3 N@C 80 , a metallic nitride fullerene) were prepared and characterized for their mechanical and dielectric properties using dynamic mechanical analysis (DMA) and broadband dielectric spectroscopy (BDS). Fullerene–polymer networks [C 60 ‐PU and Sc 3 N@C 80 ‐PU] having high gel fractions, good mechanical properties and thermal stabilities were produced. Polyhydroxylated fullerenes C 60 (OH) 29 and Sc 3 N@C 80 (OH) 18 were synthesized in high yield through a high‐speed vibration milling method and characterized using FTIR, matrix‐assisted laser desorption/ionization mass spectroscopy, and thermal gravimetric analysis. DMA of fullerene–PU networks indicates T g ∼ −50°C, with a sub‐ T g relaxation due to local chain motions. BDS analyses of the fullerenes, before and after hydroxylation and before incorporation into the networks, revealed one relaxation and large real permittivity (ε′) values for C 60 (OH) 29 relative to C 60 . Analogous samples for Sc 3 N@C 80 exhibit two relaxations, where the extra relaxation is attributed to motions of the cage‐encapsulated Sc 3 N clusters. ε′ values for Sc 3 N@C 80 ‐PU at a given frequency are higher than corresponding values for C 60 ‐PU, likely because of the rotationally mobile Sc 3 N encapsulates. Surface and bulk resistivities of fullerene–PU networks were found to have a modest dependence on relative humidity. Capacitance versus voltage characteristics of the fullerene–PUs were also studied in the range of the applied dc bias voltage of −30 to +30 v. It is generally concluded, based on all the evidence that this class of materials can be rendered quite polarizable and could be used as high dielectric permittivity materials in capacitance applications. © 2014 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2014 , 131 , 40577.