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Interfacial modification of single‐walled carbon nanotubes for high‐loading‐reinforced polypropylene composites
Author(s) -
Liu Siyang,
Wang Zhe,
Lu Guoming,
Wang Yue,
Zhang Yue,
He Xiaodan,
Zhao Lixia,
Li Zewen,
Xuan Lichun,
Zhao Dongyu
Publication year - 2014
Publication title -
journal of applied polymer science
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.575
H-Index - 166
eISSN - 1097-4628
pISSN - 0021-8995
DOI - 10.1002/app.39817
Subject(s) - materials science , carbon nanotube , polypropylene , thermogravimetric analysis , composite material , nanocomposite , fourier transform infrared spectroscopy , ultimate tensile strength , chemical engineering , engineering
In this article, we present a strategy for fabricating polypropylene (PP)/polypropylene‐regrafted single‐walled carbon nanotube (PP‐re‐ g ‐SWNT) composites with a high loading of single‐walled carbon nanotubes (SWNTs; 20 wt %). The PP‐re‐ g ‐SWNTs were characterized by X‐ray photoelectron, Fourier transform infrared spectroscopy, transmission electron microscopy, and thermogravimetric analysis (TGA). The PP‐re‐ g ‐SWNTs showed excellent interfacial adhesion and dispersion. Furthermore, PP molecules, about 72 wt % by mass, were homogeneously bonded onto the surface of the SWNTs according to TGA. In this hybrid nanocomposite system, the PP‐re‐ g ‐SWNTs were covalently integrated into the PP matrix and became part of the conjugated network structure (as evidenced by differential scanning calorimetry and dynamic mechanical analysis) rather than just a separate component. Accordingly, the PP/PP‐re‐ g ‐SWNT composites presented obvious improvements in mechanical properties and conductivity (from 10 −10 to 10 −2 ). Most importantly, the tensile and flexural strength of the PP/PP‐re‐ g ‐SWNT composites did not exhibit an obvious downturn with the addition of 20 wt % SWNTs; this was contrary to documented results. We believe that these new observations were due to the novel structure of the PP‐re‐ g ‐SWNTs. © 2013 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2014 , 131 , 39817.