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Lignin‐xylaric acid‐polyurethane‐based polymer network systems: Preparation and characterization
Author(s) -
Pohjanlehto Helinä,
Setälä Harri M.,
Kiely Donald E.,
McDonald Armando G.
Publication year - 2014
Publication title -
journal of applied polymer science
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.575
H-Index - 166
eISSN - 1097-4628
pISSN - 0021-8995
DOI - 10.1002/app.39714
Subject(s) - prepolymer , thermogravimetric analysis , dynamic mechanical analysis , differential scanning calorimetry , polyurethane , materials science , thermal stability , glass transition , lignin , polymer chemistry , fourier transform infrared spectroscopy , polymer , chemical engineering , composite material , chemistry , organic chemistry , physics , engineering , thermodynamics
Polyurethanes (PU) were synthesized from lignin by first preparing a prepolymer from esterified sugar‐based trihydroxyl compound xylaric acid and a 20 mol % excess of methylene diphenyl diisocyanate. The prepolymer was crosslinked with 5, 10, and 15 wt % of an industrial soda lignin, and polyethylene glycol was used to bring soft segments into the material structure. The total amount of bio‐based starting materials was as high as 35%. Evidence for the reaction between the prepolymer and lignin was observed using Fourier transform infrared spectroscopic analysis and 13 C nuclear magnetic resonance spectroscopy. The thermal properties of the materials were investigated by differential scanning calorimetry (DSC) and thermogravimetric analysis (TGA). The mechanical and viscoelastic properties of the materials were determined by dynamic mechanical analysis (DMA). The glass transition temperatures ( T g ) obtained from DSC and DMA showed a trend of increasing T g with the increasing amount of lignin. A similar trend was observed with TGA for the increasing thermal stability up to 550 o C with the increasing amount of lignin. The lignin‐polyurethanes obtained were stiff materials showing high Young's modulus values. © 2013 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2014 , 131 , 39714.