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Synthesis and characterization of fullerene functionalized poly(vinyl chloride) (PVC) and dehydrochlorinated PVC using atom Transfer Radical Addition and AIBN based fullerenation
Author(s) -
Seeponkai Narumon,
Wootthikanokkhan Jatuphorn,
Thanachayat Chanchana
Publication year - 2013
Publication title -
journal of applied polymer science
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.575
H-Index - 166
eISSN - 1097-4628
pISSN - 0021-8995
DOI - 10.1002/app.39443
Subject(s) - fullerene , vinyl chloride , polymer , polyvinyl chloride , atom transfer radical polymerization , fourier transform infrared spectroscopy , chemistry , grafting , chloride , polymer chemistry , chemical engineering , organic chemistry , polymerization , engineering , copolymer
The research presented details chemical modifications of poly(vinyl chloride) (PVC) and its derivative, dehydrochlorinated PVC (DH‐PVC) through the use of two grafting techniques, namely a normal fullerenation, using AIBN (2,2′‐Azoisobutyronitrile), and the atom transfer radical addition (ATRA). The products were characterized and the presence of new FTIR peaks at 528 and 577 cm −1 along with new 1 H‐NMR signal at 3.9 ppm, suggested that fullerenes has been grafted to the polymer molecules. Percentage of C 60 in the fullerene grated products determined by UV/Visible spectroscopy initially increased with the amount of fullerene used to a maximum value (∼5.66 % wt) before decreasing again. It was also determined that the C 60 content of the fullerene grafted PVC product prepared by using ATRA, was notably greater than that obtained using the normal fullerenation approach, regardless of the amount of C 60 used. When the dehydrochlorinated PVC was used as the starting polymer for fullerenation, the fullerene grafted DH‐PVC using ATRA, was markedly insoluble in many common solvents (THF and dichlorobenzene). This was not the cases for the fullerene grafted DHPVC prepared via an AIBN based fullerenation. Furthermore, the electrical conductivity values of the modified PVC products determined by using a four‐point probe method were found to increase linearly with the amount of C 60 present. Overall our data suggest that the suitable and efficient techniques for grafting C 60 onto PVC and DHPVC chains are ATRA and AIBN‐based fullerenation, respectively. © 2013 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 130: 2410–2421, 2013