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Investigation on high strength laser welds of polypropylene and high‐density polyethylene
Author(s) -
Juhl Thomas Brokholm,
Christiansen Jesper deClaville,
Jensen Erik Appel
Publication year - 2013
Publication title -
journal of applied polymer science
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.575
H-Index - 166
eISSN - 1097-4628
pISSN - 0021-8995
DOI - 10.1002/app.39000
Subject(s) - high density polyethylene , materials science , composite material , ultimate tensile strength , polypropylene , polyethylene , welding , crystallinity , izod impact strength test
Mechanical strength in polymer weld interfaces in semi‐crystalline high density polyethylene (HDPE) and polypropylene (PP) is investigated. The welding method investigated is through transmission laser welding (TTLW). Utilizing the TTLW process with 0.4 wt % carbon black as absorber, a lap‐joint is formed which is tested for mechanical properties using an Instron tensile testing machine. In contrast to earlier investigations, the tensile tests conclude that 89% of the strength of a HDPE/HDPE weld was developed in a PP/HDPE weld with HDPE as the absorbing part. This high weld strength is explained from: (1) a relatively low reptation time being in the millisecond range for both HDPE and PP; (2) a polymer mesh size (tube diameter ( a )) being similar to the equilibrium interpenetration depth, determined from Helfand's theory and the interaction parameter (χ); (3) The selected HDPE and PP were both metallocene catalyzed and constituted a similar crystallization temperature which is required for high crystallinity in/near the interface. © 2013 Wiley Periodicals, Inc. J. Appl. Polym. Sci., 2013