Synthesis and properties of photocross‐linked polymers of epoxidized linseed oil with different reactive diluents | Zendy

Remeikyte Ausra | Zendy; Ostrauskaite Jolita | Zendy; Grazuleviciene Violeta | Zendy

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Synthesis and properties of photocross‐linked polymers of epoxidized linseed oil with different reactive diluents

Author(s) -

Remeikyte Ausra,

Ostrauskaite Jolita,

Grazuleviciene Violeta

Publication year - 2012

Publication title -

journal of applied polymer science

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.575

H-Index - 166

eISSN - 1097-4628

pISSN - 0021-8995

DOI - 10.1002/app.38816

Subject(s) - diglycidyl ether , linseed oil , trimethylolpropane , diluent , epoxy , polymer chemistry , photoinitiator , polymer , ether , materials science , reactive extrusion , photopolymer , cyclohexane , thermal stability , bisphenol , epoxidized soybean oil , organic chemistry , chemistry , bisphenol a , polymerization , monomer , polyurethane , raw material

Cross‐linked polymers were obtained by photopolymerization of epoxidized linseed oil with different reactive diluents (3,4‐epoxycyclohexylmethyl‐3,4‐epoxycyclohexane carboxylate, 1,4‐cyclohexane dimethanol diglycidyl ether, bisphenol A diglycidyl ether, trimethylolpropane triglycidyl ether, and bis[4‐(glycidyloxy)phenyl]methane) using the mixture of triarylsulfonium hexafluoroantimonates as photoinitiator. The kinetic of photocross‐linking reactions of compositions with different concentrations of reactive diluents was investigated. The 69%–91% conversion of epoxy groups of the compositions containing reactive diluents was reached. The mechanical properties, thermal stability, and swelling in polar and nonpolar solvents of the photocross‐linked polymers were studied. © 2012 Wiley Periodicals, Inc. J. Appl. Polym. Sci., 2013

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