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Structural changes in the carbon black network in carbon‐black‐filled styrene‐butadiene rubber samples cured with a two‐step process
Author(s) -
Kato Atsushi,
Isono Yoshinobu
Publication year - 2012
Publication title -
journal of applied polymer science
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.575
H-Index - 166
eISSN - 1097-4628
pISSN - 0021-8995
DOI - 10.1002/app.38356
Subject(s) - carbon black , elongation , natural rubber , styrene butadiene , volume fraction , materials science , carbon fibers , mass fraction , composite material , polymer chemistry , fraction (chemistry) , transmission electron microscopy , copolymer , styrene , chemistry , ultimate tensile strength , polymer , organic chemistry , nanotechnology , composite number
The volume resistivity of carbon black (CB)‐filled crosslinked styrene‐butadiene rubber (SBR) samples cured in two steps and having a fixed elongation condition declined slightly when the elongation ratio (α) was 3 or smaller, whereas the value increased markedly at α = 4. Three‐dimensional transmission electron microscopy observations revealed that the closest interparticle distance between the carbon black aggregates (CB ag 's) and the CB ag number density decreased at α = 1−2 but increased at α = 4 and that the distance between the centers of gravity of the closest CB ag and the volume of CB ag increased at α = 1−3 but decreased at α = 4. Also, the fraction of crosslinked chains of the carbon black network (CB net ) was decreased with elongation, and the fraction of branched chains increased. The fraction of isolated chains in particular showed a more pronounced increase at α > 3 compared with α < 3. These results presumably imply that for the sample with α > 3, the coarsened CB ag 's were finely divided and also that the CB net was broken by elongation. © 2012 Wiley Periodicals, Inc. J. Appl. Polym. Sci., 2013